Hafnium
Hafnium is the 72nd element in the periodic table, with an atomic mass of 178.49 amu,
a density of 13.31 g/cm cubed, and electron levels of 2-8-18-32-10-2. Hafnium has a +4 valence, and
is a member of group 4B, the element directly following the lanthanide series. Hf was discovered
in 1923 by D. Coster of the Netherlands, and G. von Hevesy of Hungary. Hf melts at 2230.85 degrees C, and
boils at 4601.85 degrees C. It was named after the city in which it was discovered, Copenhagen.
(also known as Hafnia) It was first identified in zircon, which contains about 1% to 5% hafnium.
Hf is ductile with a brilliant silver luster, and its properties are influenced by the amount of zirconium
present, zirconium and hafnium being 2 of the most difficult elements to separate. Their chemistry is almost
identical, yet hafnium is about twice as dense as zirconium. When heated to 700 degrees C, Hf rapidly
absorbs hydrogen. Halogens can also react to hafnium to form tetrahalides. Hf is corrosion resistant, and is sometimes
used in lamps.
June 18, 1997
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